James's Weezing
Weezing (Japanese: マタドガス Matadogas) was the first Pokémon James appeared with in Kanto.
It first appeared in Pokémon Emergency as a Koffing. It was used constantly by James and eventually evolved into a Weezing in the episode Dig Those Diglett.
James used Koffing as a main battle Pokémon throughout most of the Kanto episodes. After getting his Victreebel, he tended to use Victreebel for actual combat and only used Weezing to create smoke to cover escapes and entrances throughout the adventures in Johto.
As Koffing, it was always happy and light-hearted. But after it evolved, it constantly looked depressed and forlorn.
In A Poached Ego Team Rocket found a poacher holding a herd of Ekans and Koffing captive in Hoenn. After freeing them James and Jessie reluctantly ordered Weezing and Arbok
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For more information on this Pokémon's species, see Weezing.