From Bulbapedia, the community-driven Pokémon encyclopedia.
TMs vary between generations; however, TMs numbered 96 to 100 were not added until Generation VI.
TM100 is:
This TM was not available before Generation VI
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DPPt
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Twinleaf Town
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N/A
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N/A
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HGSS
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Currently Unknown
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N/A
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N/A
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PBR*
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Currently Unknown
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N/A
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N/A
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MDTDS
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Currently Unknown
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N/A
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N/A
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MDBSL
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Currently Unknown
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N/A
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N/A
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BW
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Currently Unknown
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N/A
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B2W2
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Currently Unknown
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N/A
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MDGtI
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Currently Unknown
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N/A
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N/A
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SMD
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Currently Unknown
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N/A
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N/A
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SM
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Currently Unknown
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N/A
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USUM
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Currently Unknown
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N/A
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SwSh
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Currently Unknown
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N/A
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BDSP
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Currently Unknown
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N/A
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N/A
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